https://www.youtube.com/watch?v=Mj2QOpQkSfI
TL;DR — Hot objects glow because the excess energy within their molecules causes electrons to change energy states, emitting photons of light. This phenomenon, known as blackbody radiation, is observed when objects reach temperatures high enough for these emitted photons to fall within the visible spectrum. The intensity and color of the glow depend on the object's temperature and the available electron energy levels.
Takeaway — Objects glow when heated because the increased internal energy causes electrons to emit light as they transition between energy levels.